Specific Interactions and the Miscibility of Polymer Blends

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Michael M. Coleman (Pennsylvania State University, University Park, USA) Paul C. Painter (Pennsylvania State University, University Park, USA)

Specific Interactions and the Miscibility of Polymer Blends

Michael M. Coleman (Pennsylvania State University, University Park, USA), Paul C. Painter (Pennsylvania State University, University Park, USA), John F. Graf

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English

CRC Press
23 September 2019

Polymer chemistry; Chemical engineering; Environmental science, engineering & technology

This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area.

FROM THE AUTHORS' PREFACE:

During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility.

Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants.

Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems.

Accor

By: Michael M. Coleman (Pennsylvania State University University Park USA), Paul C. Painter (Pennsylvania State University, University Park, USA), John F. Graf
Imprint: CRC Press
Country of Publication: United Kingdom
Dimensions: Height: 234mm, Width: 156mm,
Weight: 952g
ISBN: 9780367401511
ISBN 10: 0367401517
Pages: 516
Publication Date: 23 September 2019
Audience: Professional and scholarly , Undergraduate
Format: Paperback
Publisher's Status: Active

Coleman, Michael M.; Painter, Paul C.; Graf, John F.