Heterogenous Photochemical Electron Transfer

Michael Gratzel

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Hardback

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English

CRC Press
29 November 2017

Chemical physics; Life sciences: general issues

The present monograph attempts to unify these diverse and exciting new developments within a common framework. First, the physical principles underlying heterogenous electron-transfer processes are outlined in a concise way and are compared to the homogeneous counterpart. This analysis includes the notion of the Fermi level in liquids and solids as well as the distribution of electronic energy levels in solids and liquids. A comparison is made between the salient kinetic features of homogeneous and heterogeneous electron transfer reactions. This establishes the basis for the subsequent treatment of the transduction of excitation energy and photo-initiated electron transfer in organized molecular assemblies, such as micelles, vesicles and monolayers. Transmembrane redox processes are critically reviewed. Particular attention is given to semiconductor electrodes and particles. This includes a discussion of quantum size effects, the nature of space charge layers as well as surface states and the dynamics of charge carrier-induced redox reactions at the semiconductor solution interface. These processes are of fundamental importance in such diverse fields as photochromism, electrochromic displays, electroreprography and photography, information storage, photocatalysis, photodegradation of paints, and solar energy conversion.

By: Michael Gratzel
Imprint: CRC Press
Country of Publication: United Kingdom
Dimensions: Height: 254mm, Width: 178mm,
Weight: 453g
ISBN: 9781315894102
ISBN 10: 1315894106
Pages: 170
Publication Date: 29 November 2017
Audience: College/higher education , General/trade , Primary , ELT Advanced
Format: Hardback
Publisher's Status: Active

Gratzel, Michael