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Enantioselective Electrochemical C–H Activation Enabled by Sustainable 3d Transition Metal Catalysis by Sven Erik Peters at Abbey's Bookshop,
Enantioselective Electrochemical C–H Activation Enabled by Sustainable 3d Transition Metal Catalysis
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Sven Erik Peters

Enantioselective Electrochemical C–H Activation Enabled by Sustainable 3d Transition Metal Catalysis

Sven Erik Peters

$251.95   $201.58

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English
Springer Spektrum
22 February 2025
Materials science
Series: BestMasters
Enantioselective metallaelectro-catalyzed C─H activation represents an innovative strategy for enabling the transition of organic synthesis to a more resource-economic mode of operation. It circumvents substrate prefunctionalization by directly exploiting otherwise inert C─H bonds to construct complex three-dimensional scaffolds from simple molecular building blocks. Furthermore, the mild electrocatalytic conditions evade chemical oxidants, while producing molecular hydrogen as the sole by-product, enabling the connection of organic synthesis to a possible future decentralized green hydrogen economy.

Still, disclosed methodologies predominantly rely on noble metal catalysts. Examples using earth-abundant 3d transition metals remain scarce despite the substantially improved ecological and economic implications and diminished toxicity. This work addresses this shortcoming by investigating the first enantioselective nickelaelectro-catalyzed C─H activation and various cobaltaelectro-catalyzed conversions. On this occasion, the synthetic versatility is examined and various mechanistic experiments are presented for fostering future developments.
By:  
Imprint:   Springer Spektrum
Country of Publication:   Germany
Dimensions:   Height: 210mm,  Width: 148mm, 
ISBN:   9783658471095
ISBN 10:   3658471093
Series:   BestMasters
Pages:   96
Publication Date:  
Audience:   Professional and scholarly ,  Undergraduate
Format:   Paperback
Publisher's Status:   Active

Sven Erik Peters is researching enantioselective 3d transition metal-catalyzed C─H activations with electrochemical strategies at the Wöhler Research Institute for Sustainable Chemistry (WISCh) under the direction of Prof. Dr. Lutz Ackermann. He completed his Master's thesis here and started his doctorate in this field afterwards.

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