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Electrophosphorescent Materials and Devices

Mark Thompson

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Hardback

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English
Jenny Stanford Publishing
14 December 2023
Organic LEDs (OLEDs) in mobile displays have been in large-scale production for over a decade, and OLED-based televisions are rapidly gaining traction in the marketplace. OLEDs are on the verge of entering the solid-state lighting market in a big way. The OLED technology gives higher color purity and is more efficient than any of the competing technologies. When produced at scale, OLEDs are also economical. A key limitation in the development of OLEDs was the efficient conversion of all of the electrical energy put into the device into light. Until the late 1990s, the maximum efficiency of OLEDs was limited to 25% (photons/electrons), but this limitation was removed and OLEDs with 100% efficiency were reported in the early 2000s. This advance in OLED technology was driven by the author of this book. He and his collaborators developed electrophosphorescence, which is essential in reaching the 100% efficiency that is now commonplace in commercial devices.

Edited by:  
Imprint:   Jenny Stanford Publishing
Country of Publication:   Singapore
Dimensions:   Height: 229mm,  Width: 152mm, 
Weight:   2.220kg
ISBN:   9789814877343
ISBN 10:   9814877344
Pages:   1082
Publication Date:  
Audience:   Professional and scholarly ,  Undergraduate
Format:   Hardback
Publisher's Status:   Active
1. Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices Marc A. Baldo, D. F. O’Brien, Y. You, A. Shoustikov, Scott Sibley, Mark E. Thompson, and Stephen R. Forrest 2. Improved Energy Transfer in Electrophosphorescent Devices D. F. O’Brien, Marc A. Baldo, Mark E. Thompson, and Stephen R. Forrest 3. Efficient, Saturated Red Organic Light Emitting Devices Based on Phosphorescent Platinum(II) Porphyrins Raymond C. Kwong, Scott Sibley, Timur Dubovoy, Marc Baldo, Stephen R. Forrest, and Mark E. Thompson 4. Excitonic Singlet-Triplet Ratio in a Semiconducting Organic Thin Film Marc A. Baldo, D. F. O’Brien, Mark E. Thompson, and Stephen R. Forrest 5. Very High-Efficiency Green Organic Light-Emitting Devices Based on Electrophosphorescence Marc A. Baldo, Sergey Lamansky, Paul E. Burrows, Mark E. Thompson, and Stephen R. Forrest 6. Organic Light-Emitting Devices Based on Phosphorescent Hosts and Dyes Raymond C. Kwong, Sergey Lamansky, and Mark E. Thompson 7. High-Efficiency Organic Electrophosphorescent Devices with tris(2-Phenylpyridine)Iridium Doped into Electron-Transporting Materials Chihaya Adachi, Marc A. Baldo, Stephen R. Forrest, and Mark E. Thompson 8. High-Efficiency Fluorescent Organic Light-Emitting Devices Using a Phosphorescent Sensitizer Marc A. Baldo, Mark E. Thompson, and Stephen R. Forrest 9. Nearly 100% Internal Phosphorescence Efficiency in an Organic Light Emitting Device Chihaya Adachi, Marc A. Baldo, Mark E. Thompson, and Stephen R. Forrest 10. Endothermic Energy Transfer: A Mechanism for Generating Very Efficient High-Energy Phosphorescent Emission in Organic Materials Chihaya Adachi, Raymond C. Kwong, Peter Djurovich, Vadim Adamovich, Marc A. Baldo, Mark E. Thompson, and Stephen R. Forrest 11. High-Efficiency Yellow Double-Doped Organic Light-Emitting Devices Based on Phosphor-Sensitized Fluorescence Brian W. D’Andrade, Marc A. Baldo, Chihaya Adachi, Jason Brooks, Mark E. Thompson, and Stephen R. Forrest 12. High-Efficiency Red Electrophosphorescence Devices Chihaya Adachi, Marc A. Baldo, Stephen R. Forrest, Sergey Lamansky, Mark E. Thompson, and Raymond C. Kwong 13. Highly Phosphorescent Bis-Cyclometalated Iridium Complexes: Synthesis, Photophysical Characterization, and Use in Organic Light Emitting Diodes Sergey Lamansky, Peter Djurovich, Drew Murphy, Feras Abdel-Razzaq, Hae-Eun Lee, Chihaya Adachi, Paul E. Burrows, Stephen R. Forrest, and Mark E. Thompson 14. Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes Sergey Lamansky, Peter Djurovich, Drew Murphy, Feras Abdel-Razzaq, Raymond Kwong, Irina Tsyba, Manfred Bortz, Becky Mui, Robert Bau, and Mark E. Thompson 15. Synthesis and Characterization of Phosphorescent Cyclometalated Platinum Complexes Jason Brooks, Yelizaveta Babayan, Sergey Lamansky, Peter I. Djurovich, Irina Tsyba, Robert Bau, and Mark E. Thompson 16. White Light Emission Using Triplet Excimers in Electrophosphorescent Organic Light-Emitting Devices Brian W. D’Andrade, Jason Brooks, Vadim Adamovich, Mark E. Thompson, and Stephen R. Forrest 17. Electrophosphorescent p–i–n Organic Light-Emitting Devices for Very-High-Efficiency Flat-Panel Displays Martin Pfeiffer, Stephen R. Forrest, Karl Leo, and Mark E. Thompson 18. Cyclometalated Ir Complexes in Polymer Organic Light-Emitting Devices Sergey Lamansky, Peter I. Djurovich, Feras Abdel-Razzaq, Simona Garon, Drew L. Murphy, and Mark E. Thompson 19. High Efficiency Single Dopant White Electrophosphorescent Light Emitting Diodes Vadim Adamovich, Jason Brooks, Arnold Tamayo, Alex M. Alexander, Peter I. Djurovich, Brian W. D’Andrade, Chihaya Adachi, Stephen R. Forrest, and Mark E. Thompson 20. High Operational Stability of Electrophosphorescent Devices Raymond C. Kwong, Matthew R. Nugent, Lech Michalski, Tan Ngo, Kamala Rajan, Yeh-Jiun Tung, Michael S. Weaver, Theodore X. Zhou, Michael Hack, Mark E. Thompson, Stephen R. Forrest, and Julie J. Brown 21. Controlling Exciton Diffusion in Multilayer White Phosphorescent Organic Light Emitting Devices Brian W. D’Andrade, Mark E. Thompson, and Stephen R. Forrest 22. Blue Organic Electrophosphorescence Using Exothermic Host–Guest Energy Transfer Russell J. Holmes, Stephen R. Forrest, Yeh-Jiun Tung, Raymond C. Kwong, Julie J. Brown, Simona Garon, and Mark E. Thompson 23. Efficient, Deep-Blue Organic Electrophosphorescence by Guest Charge Trapping Russell J. Holmes, Brian W. D’Andrade, Stephen R. Forrest, Xiaofan Ren, Jian Li, and Mark E. Thompson 24. Synthesis and Characterization of Facial and Meridional Tris-cyclometalated Iridium(III) Complexes Arnold B. Tamayo, Bert D. Alleyne, Peter I. Djurovich, Sergey Lamansky, Irina Tsyba, Nam N. Ho, Robert Bau, and Mark E. Thompson 25. Phosphorescence Quenching by Conjugated Polymers Madhusoodhanan Sudhakar, Peter I. Djurovich, Thieo E. Hogen-Esch, and Mark E. Thompson 26. Simultaneous Light Emission from a Mixture of Dendrimer Encapsulated Chromophores: A Model for Single-Layer Multichromophoric Organic Light-Emitting Diodes Paul Furuta, Jason Brooks, Mark E. Thompson, and Jean M. J. Fréchet 27. Ultrahigh Energy Gap Hosts in Deep Blue Organic Electrophosphorescent Devices Xiaofan Ren, Jian Li, Russell J. Holmes, Peter I. Djurovich, Stephen R. Forrest, and Mark E. Thompson 28. Saturated Deep Blue Organic Electrophosphorescence Using a Fluorine-Free Emitter Russell J. Holmes, Stephen R. Forrest, Tissa Sajoto, Arnold Tamayo, Peter I. Djurovich, Mark E. Thompson, Jason Brooks, Yeh-Jiun Tung, Brian W. D’Andrade, Michael S. Weaver, Raymond C. Kwong, and Julie J. Brown 29. Excimer and Electron Transfer Quenching Studies of a Cyclometalated Platinum Complex Biwu Ma, Peter I. Djurovich, and Mark E. Thompson 30. Synthetic Control of Excited-State Properties in Cyclometalated Ir(III) Complexes Using Ancillary Ligands Jian Li, Peter I. Djurovich, Bert D. Alleyne, Muhammed Yousufuddin, Nam N. Ho, J. Christopher Thomas, Jonas C. Peters, Robert Bau, and Mark E. Thompson 31. Cationic Bis-cyclometalated Iridium(III) Diimine Complexes and Their Use in Efficient Blue, Green, and Red Electroluminescent Devices Arnold B. Tamayo, Simona Garon, Tissa Sajoto, Peter I. Djurovich, Irina M. Tsyba, Robert Bau, and Mark E. Thompson 32. Blue and Near-UV Phosphorescence from Iridium Complexes with Cyclometalated Pyrazolyl or N-Heterocyclic Carbene Ligands Tissa Sajoto, Peter I. Djurovich, Arnold Tamayo, Muhammed Yousufuddin, Robert Bau, Mark E. Thompson, Russell J. Holmes, and Stephen R. Forrest 33. Synthetic Control of Pt··· Pt Separation and Photophysics of Binuclear Platinum Complexes Biwu Ma, Jian Li, Peter I. Djurovich, Muhammed Yousufuddin, Robert Bau, and Mark E. Thompson 34. Platinum Binuclear Complexes as Phosphorescent Dopants for Monochromatic and White Organic Light-Emitting Diodes Biwu Ma, Peter I. Djurovich, Simona Garon, Bert Alleyne, and Mark E. Thompson 35. Management of Singlet and Triplet Excitons for Efficient White Organic Light-Emitting Devices Yiru Sun, Noel C. Giebink, Hiroshi Kanno, Biwu Ma, Mark E. Thompson, and Stephen R. Forrest 36. Highly Efficient, Near-Infrared Electrophosphorescence from a Pt–Metalloporphyrin Complex Carsten Borek, Kenneth Hanson, Peter I. Djurovich, Mark E. Thompson, Kristen Aznavour, Robert Bau, Yiru Sun, Stephen R. Forrest, Jason Brooks, Lech Michalski, and Julie Brown 37. Intrinsic Luminance Loss in Phosphorescent Small-Molecule Organic Light Emitting Devices due to Bimolecular Annihilation Reactions Noel C. Giebink, Brian W. D’Andrade, Michael S. Weaver, P. B. Mackenzie, Julie J. Brown, Mark E. Thompson, and Stephen R. Forrest 38. Blue Light Emitting Ir(III) Compounds for OLEDs: New Insights into Ancillary Ligand Effects on the Emitting Triplet State Andreas F. Rausch, Mark E. Thompson, and Hartmut Yersin 39. Temperature Dependence of Blue Phosphorescent Cyclometalated Ir(III) Complexes Tissa Sajoto, Peter I. Djurovich, Arnold B. Tamayo, Jonas Oxgaard, William A. Goddard III, and Mark E. Thompson 40. Study of Energy Transfer and Triplet Exciton Diffusion in Hole-Transporting Host Materials Chao Wu, Peter I. Djurovich, and Mark E. Thompson 41. Synthesis and Characterization of Phosphorescent Three-Coordinate Cu(I)–NHC Complexes Valentina A. Krylova, Peter I. Djurovich, Matthew T. Whited, and Mark E. Thompson 42. A Codeposition Route to CuI–Pyridine Coordination Complexes for Organic Light-Emitting Diodes Zhiwei Liu, Munzarin F. Qayyum, Chao Wu, Matthew T. Whited, Peter I. Djurovich, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, and Mark E. Thompson 43. Structural and Photophysical Studies of Phosphorescent Three-Coordinate Copper(I) Complexes Supported by an N-Heterocyclic Carbene Ligand Valentina A. Krylova, Peter I. Djurovich, Jacob W. Aronson, Ralf Haiges, Matthew T. Whited, and Mark E. Thompson 44. Phosphorescence versus Thermally Activated Delayed Fluorescence: Controlling Singlet–Triplet Splitting in Brightly Emitting and Sublimable Cu(I) Compounds Markus J. Leitl, Valentina A. Krylova, Peter I. Djurovich, Mark E. Thompson, and Hartmut Yersin 45. Control of Emission Colour with N-Heterocyclic Carbene (NHC) Ligands in Phosphorescent Three-Coordinate Cu(I) Complexes Valentina A. Krylova, Peter I. Djurovich, Brian L. Conley, Ralf Haiges, Matthew T. Whited, Travis J. Williams, and Mark E. Thompson 46. Synthesis and Characterization of Phosphorescent Platinum and Iridium Complexes with Cyclometalated Corannulene John W. Facendola, Martin Seifrid, Jay Siegel, Peter I. Djurovich, and Mark E. Thompson 47. Understanding and Predicting the Orientation of Heteroleptic Phosphors in Organic Light-Emitting Materials Matthew J. Jurow, Christian Mayr, Tobias D. Schmidt, Thomas Lampe, Peter I. Djurovich, Wolfgang Brütting, and Mark E. Thompson 48. Deep Blue Phosphorescent Organic Light-Emitting Diodes with Very High Brightness and Efficiency Jaesang Lee, Hsiao-Fan Chen, Thilini Batagoda, Caleb Coburn, Peter I. Djurovich, Mark E. Thompson, and Stephen R. Forrest 49. Hot Excited State Management for Long-Lived Blue Phosphorescent Organic Light-Emitting Diodes Jaesang Lee, Changyeong Jeong, Thilini Batagoda, Caleb Coburn, Mark E. Thompson, and Stephen R. Forrest 50. Eliminating Nonradiative Decay in Cu(I) Emitters: > 99% Quantum Efficiency and Microsecond Lifetime Rasha Hamze, Jesse L. Peltier, Daniel Sylvinson, Moonchul Jung, Jose Cardenas, Ralf Haiges, Michele Soleilhavoup, Rodolphe Jazzar, Peter I. Djurovich, Guy Bertrand, and Mark E. Thompson 51. Rapid Multiscale Computational Screening for OLED Host Materials Daniel Sylvinson M. R., Hsiao-Fan Chen, Lauren M. Martin, Patrick J. G. Saris, and Mark E. Thompson 52. “Quick-Silver” from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes Rasha Hamze, Shuyang Shi, Savannah C. Kapper, Daniel Sylvinson Muthiah Ravinson, Laura Estergreen, Moon-Chul Jung, Abegail C. Tadle, Ralf Haiges, Peter I. Djurovich, Jesse L. Peltier, Rodolphe Jazzar, Guy Bertrand, Stephen E. Bradforth, and Mark E. Thompson 53. Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic Carbenes Shuyang Shi, Moon Chul Jung, Caleb Coburn, Abegail Tadle, Daniel Sylvinson M. R., Peter I. Djurovich, Stephen R. Forrest, and Mark E. Thompson 54. Platinum-Functionalized Random Copolymers for Use in Solution-Processible, Efficient, Near-White Organic Light-Emitting Diodes Paul T. Furuta, Lan Deng, Simona Garon, Mark E. Thompson, and Jean M. J. Fréchet

Mark E. Thompson received his BS in chemistry in 1980 from the University of California, Berkeley, and his PhD in chemistry in 1985 from the California Institute of Technology. He was a postdoctoral fellow at Oxford University and is currently the Ray R. Irani Chair of Chemistry at the University of Southern California. His research involves the study of materials and devices for electroluminescence, photovoltaics and solar cells, chemical/biological sensing, and catalysis. Prof. Thompson is the author of approximately 400 papers in refereed professional journals and holds more than 250 patents primarily in the areas of optoelectronic applications, such as light-emitting devices and solar cells.

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