Organometallic Chemistry and Catalysis

Didier Astruc

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English

Springer-Verlag Berlin and Heidelberg GmbH & Co. K
23 August 2016

Inorganic chemistry; Organometallic chemistry; Catalysis

This tutorial volume covers the basic and advanced aspects of organometallic chemistry of all metals and related catalysis topics. In order to present a comprehensive view of the subject, it examines the historical background, as well as concepts (including structures of mono- and polymetallic complexes), molecular orbitals, reactivity, implications in biology and applications to organic synthesis and catalysis. The catalysis section includes the challenging activation and functionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Chapter-end summaries and exercises support self- and group study, with solutions included at the end of the book. 500 selected references complement the text for further reading. Chapter-length treatment of green chemistry, plus many recent international research results, round off this highly accessible textbook.

By: Didier Astruc
Imprint: Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Country of Publication: Germany
Edition: Softcover reprint of the original 1st ed. 2007
Dimensions: Height: 254mm, Width: 178mm,
Weight: 1.171kg
ISBN: 9783662500866
ISBN 10: 3662500868
Pages: 608
Publication Date: 23 August 2016
Audience: Professional and scholarly , Undergraduate
Format: Paperback
Publisher's Status: Active

History of Organometallic Chemistry.- History of Organometallic Chemistry.- Structures of the Transition-Metal Complexes.- Monometallic Transition-Metal Complexes.- Bimetallic Transition-Metal Complexes and Clusters.- The Stoichiometric Reactions of Transition-Metal Complexes.- Redox Reactions, Oxidative Addition and ?-Bond Metathesis.- Reactions of Nucleophiles and Electrophiles with Complexes.- Ligand Substitution Reactions.- Insertion and Extrusion Reactions.- The Main Families of Organometallic Complexes.- Metal Carbonyls and Complexes of Other Monohapto L Ligands.- Metal-Alkyl and -Hydride Complexes and Other Complexes of Monohapto X Ligands.- Metal-Carbene and -Carbyne Complexes and Multiple Bonds with Transition Metals.- ? Complexes of Mono- and Polyenes and Enyls.- Metallocenes and Sandwich Complexes.- Ionic and Polar Metal-Carbon Bonds: Alkali and Rare-Earth Complexes.- Covalent Chemistry of the Organoelements of Frontier (11, 12) and Main (13–16) Groups.- Catalysis.- to Catalysis.- Hydrogenation and Hydroelementation of Alkenes.- Transformations of Alkenes and Alkynes.- Oxidation of Olefins.- C-H Activation and Functionalization of Alkanes and Arenes.- Carbonylation and Carboxylation Reactions.- Bio-Organometallic Chemistry: Enzymatic Catalysis.- Heterogeneous Catalysis.- Applications in Organic Synthesis.- Organometallic Complexes in Organic Synthesis Examples of Applications.

Reviews for Organometallic Chemistry and Catalysis

"Aus den Rezensionen: ""Das erfolgreiche franz�sische Lehrbuch 'Chimie Organom�tallique' liegt nun �berarbeitet in englischer �bersetzung vor. Es soll als Begleitung zur ersten Vorlesung in metallorganischer Chemie dienen und fortgeschrittenen Studenten durch umfangreiche Literaturzitate den Einstieg in spezielle Themen erleichtern. Deshalb geht der Autor deutlich �ber die reinen Grundlagen hinaus und versucht, dem Leser die metallorganische Chemie in ihrer ganzen Breite (und dar�ber hinaus) mit aktuellen Entwicklungen vorzustellen und schmackhaft zu machen. ... Gliederung und Aufbau sind f�r ein Lehrbuch sehr gut gew�hlt. Der Stoffumfang ist keinesfalls zu knapp und die detaillierte Beschreibung der ersten beiden Teile wird einem guten Lehrbuch voll gerecht ..."" (Doris Kunz, in: Nachrichten aus der Chemie, 2008. Vol. 56, Issue 4, S. 469)"