Nanomaterials and nanocomposite materials have been developed as corrosion inhibitors and are the most noble and effective alternatives to traditional organic corrosion inhibitors. Nanomaterials provide reasonably high anticorrosive activity in both aqueous and solution phases. A unified approach to this task is lacking, however, which highlights the role of all disciplines involved in the creation and use of corrosion protection coatings for metals. Fouling is the process of accumulating unwanted material that is mostly non-living and comprised of detritus and organic or inorganic compounds, or organisms, such as tiny viruses up to giant kelps. This book covers both the processes of biofouling and anti(bio)fouling, and the devices that stop the biofouling process. This book provides a missing synopsis by providing an understanding of the anticorrosive and anti-biofouling effects of nanomaterials and nanocomposites under different environments. It features an up-to-date picture of the quality and chemistry of a substrate surface, its proper preparation by conversion treatment, the function of resins and anticorrosive pigments in paints, and novel concepts for corrosion protection.
Preface xvii Acknowledgements xix 1 Antifouling Nanoparticle Coatings for Post-Harvest Food Preservation 1 Gokuraju Thriveni, Hari Murthy and CH. Anusha 1.1 Introduction 2 1.2 Materials Support Post-Harvest 2 1.3 Computational Methods to Envision the Interaction of Food Residuals with Coated Nanolayers Through Sensing 5 1.4 Feasible Research Implications to Address the Shortcomings in Food Preservation 7 2 Toward Stable Electrochemical Water Splitting: Anticorrosive Properties of Transition Metal–Based Electrocatalytic Coatings 13 Kaushal Gavankar, Suchitra Sapakal and Anamika V. Kadam 2.1 Introduction 14 2.2 Corrosion Mechanisms 16 2.3 Methods to Prevent Corrosion 20 2.4 Anticorrosive Catalytic Coating 23 2.5 Carbon-Based Anticorrosive Catalytic Coatings 30 2.6 Discussion 31 2.7 Conclusion 34 3 Ionic Liquids in Marine Anti-Fouling Coatings 43 Samantha Taylor, Sajith K. Baiju, Madison K. McQuinlan and Matthew G. Cowan 3.1 Introduction 44 3.2 Current Anti-Fouling Design Strategies 50 3.3 Poly(Ionic Liquids) as Anti-Fouling Coatings 58 4 Inorganic Nanomaterial Coating to Prevent Biofouling 77 Anju T. R., Mariat George and Rose Mary Jose 4.1 Introduction 78 4.2 Major Industries Affected by Biofouling 80 4.3 Conventional Antifouling Coatings and their Demerits 81 4.4 Nanomaterials as Antifoulants: Properties and Mechanisms 83 4.5 Types of Nanomaterials Used as Antifoulants 85 4.6 Inorganic Nanomaterials as Antifoulant 85 4.7 Impact and Challenges of Inorganic Nanomaterials as Antifoulants 101 4.8 Conclusion 101 5 Thin Film Transparent Conducting Oxides and its Anticorrosion and Surface Protection Applications: A Review 109 Balaprakash V., Thangavel K., Mahitha Mohan, Gowrisankar P. and Sakthivel R. 5.1 About Transparent Conducting Oxides 110 5.2 Electrical Properties of TCOs 110 5.3 Optical Properties of TCO 112 5.4 Need of TCO for Solar Cells and Optoelectronic Devices 115 5.5 Requirements of TCO 116 5.6 Commonly Used TCO Materials 116 5.7 Application of TCOs 117 5.8 Anti-Corrosion and Surface Protection Application of Doped Zinc Oxide–Based TCO Materials 117 5.9 NZO Coating Over Stainless Steel 118 5.10 Conclusion 124 6 Integrated Anticorrosion and Antifouling Coatings 129 Ankita Kumari, Nirmala Kumari Jangid, Sudesh Kumar, Rekha Sharma and Navjeet Kaur 6.1 Introduction 130 6.2 Mechanisms of Corrosion and Biofouling 131 6.3 Recent Developments in Integrated Anticorrosion Coatings and Antifouling Coatings 133 6.4 PNCs Nanocoatings (Polymer Nanocomposites Coatings) 138 6.5 Marine Environment Durability Test of IAACs 140 6.6 Evaluation of Various IAACs and Difficulties 140 6.7 Conclusion and Outlook 141 7 EIS Study of Anticorrosive Nanocomposite Films 155 Vandana Shinde 7.1 Importance of Organic-Inorganic Nanocomposite Coatings 156 7.2 EIS: Brief Basic Principle and Introductions 160 7.3 EIS Data Analysis: Fitting the Equivalent Electronic Circuit, Introduction of the Various Circuit Parameters Its Physics 176 7.4 EIS in Anticorrosive Modern Nanocomposite Coatings and Assessment of Corrosion Protection Performance 198 7.5 Conclusions 202 8 Graphene-Based Coating on Mild Steel for Improving Anticorrosion and Microhardness Behavior: A Review 211 Sunita Dhar, Tapan Dash, Ashok Kumar Sahu, Sushree Subhadarshinee Mohapatra, Nibedita Mohanty, Shubhra Bajpai, Tapan Kumar Rout and Surendra Kumar Biswal 8.1 Introduction of Graphene 212 8.2 Synthesis Mechanism of Graphene Derivatives 215 8.3 Typical Characterizations of Graphene Derivatives 217 8.4 Anticorrosion Mechanisms of Graphene Derivatives and Their Composites 224 8.5 Anticorrosion Behavior of Graphene Derivative Coating on Mild Steel 229 8.6 Microhardness Behavior of Graphene Derivative Coating on Mild Steel 236 8.7 Conclusions 237 9 Bioinspired Strategies for Corrosion Protection and Antifouling Coatings 251 K. R. C. Soma Raju, Aarti Gautam, Ramay Patra, K. Srinivasa Rao, K.V. Gobi and R. Subasri 9.1 Introduction 252 9.2 Conclusions 278 10 Implementation of Nanotechnology in Anticorrosion Material Development for Food Packaging 287 Aparna Ray Sarkar, Dwaipayan Sen and Pramita Sen 10.1 Introduction 288 10.2 Synthesis of Nanoclay-Based Composites for Food Packaging 288 10.3 Metal Nanoparticle-Based Composites 294 10.4 Synthesis of Biopolymer-Based Packaging Material 296 10.5 Structural Features of Different Nanocomposites 298 10.6 Application of Different Nanomaterials in Canned Food Packaging 307 10.7 Concluding Remark 314 11 Development and Characterization of Nanostructured Thin Films for Corrosion Control Applications 323 M. Geetha Devi, R. Senthilkumar and Hebatallah Al Jabri 11.1 Introduction 324 11.2 Various Forms of Corrosion in the Petroleum Industry 326 11.3 Corrosion’s Effects on Various Equipment Used in the Petrochemical Industry 329 11.4 Conventional Corrosion Control Techniques 333 11.5 The Role of Nanotechnology in Corrosion Control 337 11.6 Application of Nanocomposite Thin Films in Corrosion Control 340 11.7 Results and Discussion 342 11.8 Conclusion 346 11.9 Future Scope 346 11.10 Challenges 347 12 Anticorrosion and Antifouling Coating Materials 353 N. Haridharan and R. V. Shiva Kumar 12.1 Introduction 354 12.2 Key Issues in the Formulation of Anticorrosive Materials 366 12.3 Formulating a Good Model for Leaching 375 12.4 The Advent of Nanotechnology 390 12.5 Summary of the Current Developments 393 12.6 Conclusion 396 13 Metal(II) Complexes as Potential Anticorrosion and Antifouling Agents—A Review 399 Asha M. S., Zabiulla, Othbert Pinto, Arjun S. R., Alen Eldose and Sangamesha M. A. 13.1 Introduction 400 13.2 Outline and Mechanism of Metal(II) Complexes as Corrosion Inhibitors 401 13.3 Outline of Metal Complexes as Antifouling Agents 409 13.4 Conclusion 415 14 Thermodynamic Modeling of Carbonaceous Coating of Oxides and Sulfides Thin Films Grown by CVD for Enhancing Surface Quality 425 Kranthi Kumar Vaidyula, Sukanya Dhar, Anjali Lalithambika and S. A. Shivashankar 14.1 Introduction 426 14.2 Experimental 426 14.3 Results and Discussion 428 14.4 Conclusions 432 15 Metal Nanoparticles: Biosynthesis Approach and Bio-Packaging Application 435 Priti Chaware, Amol Nande, J. D. Punde, K. G. Rewatkar and S. J. Dhoble 15.1 Introduction 436 15.2 Synthesis of NPs 438 15.3 Characterization of Nanoparticles 441 15.4 Concluding Remarks 449 16 Statistical Data Analysis of Anticorrosion and Antifouling: Unveiling Insights from Performance and Trends 459 Preetham Noel P., Kukatlapalli Pradeep Kumar, Mani Joseph P. and Vinay Jha Pillai 16.1 Introduction 460 16.2 Literature 460 16.3 Results and Discussion 466 16.4 Conclusion 471 17 Comprehensive Data Analysis of Anticorrosion, Antifouling Agents, and the Efficiency of Corrosion Inhibitors in CO2 Pipelines 475 Vineeth Simhadri, Kukatlapalli Pradeep Kumar, Vijaya P. and Vinai George Biju 17.1 Introduction 476 17.2 Literature Review 477 17.3 Results and Discussion 486 17.4 Conclusion 494 References 495 Index 497
Hari Murthy, PhD., finished his Ph.D. on novel anticorrosion materials at the University of Canterbury, New Zealand. He is an assistant professor in the Department of Electronics and Communication Engineering, CHRIST (Deemed to be University), Bangalore, India. His research interests include data engineering and material science. He has served as part of the program committee for several international conferences organized by the university. Vinay Jha Pillai, PhD., is an assistant professor in the Department of Electronics and Communication Engineering, CHRIST (Deemed to be University), Kengeri Campus, Bangalore, India. His primary research is in the early detection of breast cancer using optical imaging and holds two patents related in the subject. He is also exploring the domain of sensors for extracting coating parameters, especially for thermal barrier coatings which have a wide application in the field of corrosion and biofouling inhibitors. Kukatlapalli Pradeep Kumar, PhD., at an associate professor and data science program coordinator at Christ University, Bangalore, India. One of his research areas is in the field of data science for corrosion engineering where novel methods for corrosion inhibition based on data science techniques for correlating simulation predictions and molecular structures are in high demand. Matthew Cowan, PhD., is a faculty member in the Department of Chemical and Processing Engineering at the University of Canterbury, New Zealand. As a materials chemist, his main research interests are in the application of ionic liquids and ionic polymers for anti-fouling applications as well as efficient process designs for industrial gas separations. He is the author of more than 30 publications.
