Energy-Level Control at Hybrid Inorganic/Organic Semiconductor Interfaces

Raphael Schlesinger

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English

Springer International Publishing AG
01 December 2016

Spectrum analysis, spectrochemistry, mass spectrometry; Surface chemistry & adsorption; Semi-conductors & super-conductors

Series: Springer Theses

This work investigates the energy-level alignment of hybrid inorganic/organic systems (HIOS) comprising ZnO as the major inorganic semiconductor. In addition to offering essential insights, the thesis demonstrates HIOS energy-level alignment tuning within an unprecedented energy range. (Sub)monolayers of organic molecular donors and acceptors are introduced as an interlayer to modify HIOS interface-energy levels. By studying numerous HIOS with varying properties, the author derives generally valid systematic insights into the fundamental processes at work. In addition to molecular pinning levels, he identifies adsorption-induced band bending and gap-state density of states as playing a crucial role in the interlayer-modified energy-level alignment, thus laying the foundation for rationally controlling HIOS interface electronic properties. The thesis also presents quantitative descriptions of many aspects of the processes, opening the door for innovative HIOS interfaces and for future applications of ZnO in electronic devices.

By: Raphael Schlesinger
Imprint: Springer International Publishing AG
Country of Publication: Switzerland
Edition: 1st ed. 2017
Dimensions: Height: 235mm, Width: 155mm, Spine: 14mm
Weight: 4.734kg
ISBN: 9783319466231
ISBN 10: 3319466232
Series: Springer Theses
Pages: 211
Publication Date: 01 December 2016
Audience: Professional and scholarly , Undergraduate
Format: Hardback
Publisher's Status: Active

Introduction.- Fundamentals.- Theory of Experimental Methods.- Methodology and Experimental Setups.- Results and Discussion.- Conclusion.