Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes: Simple Synthetic Methods...

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Yasuomi Yamazaki

Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes

Simple Synthetic Methods for Multinuclear Complexes Using Various C-C Coupling Reactions

Yasuomi Yamazaki

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English

Springer Verlag, Singapore
13 November 2021

Organometallic chemistry; Physical chemistry

Series: Springer Theses

Summary
Details

This book presents several helpful synthetic methods for diverse multinuclear complexes. The results described can be used to selectively connect mononuclear as well as multinuclear complexes with other metal complexes to construct valuable photofunctional compounds. Using the new synthetic methods, it was possible to selectively connect several types of metal complexes in a single step under relatively mild reaction conditions. This so-called building block approach utilizes various C–C coupling reactions between metal complexes with functional groups as active moieties. Owing to the large pi-conjugation systems, the multinuclear complexes synthesized using coupling reactions showed a strong absorption ability over a wide range of visible light and long emission lifetimes, which are ideal properties for photosensitizers and light absorbers. By combining these coupling methods with the newly developed hydrogenation reactions, the binding mode of the linkers in multinuclear complexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and photosensitizers, and in light-harvesting systems. The synthetic methods and strategies presented in this book diversify not only the structures but also functions of multinuclear complexes.

By: Yasuomi Yamazaki
Imprint: Springer Verlag, Singapore
Country of Publication: Singapore
Edition: 2022 ed.
Dimensions: Height: 235mm, Width: 155mm,
Weight: 354g
ISBN: 9789811671470
ISBN 10: 9811671478
Series: Springer Theses
Pages: 105
Publication Date: 13 November 2021
Audience: Professional and scholarly , Undergraduate
Format: Hardback
Publisher's Status: Active